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What information does a COSY spectrum give?

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Correlation between ...

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The indicated hydrogens (Ha and Hb) are The indicated hydrogens (H<sub>a</sub> and H<sub>b</sub>) are   A) enantiotopic. B) diastereotopic. C) mesotopic. D) isotopic. E) none of the above.


A) enantiotopic.
B) diastereotopic.
C) mesotopic.
D) isotopic.
E) none of the above.

F) A) and D)
G) A) and B)

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An unknown compound,C3H5Cl3,gave the following proton NMR data: Doublet at 1.70 ppm (3H) Multiplet at 4.32 ppm (1H) Doublet at 5.85 ppm (1H) What is the structure of the compound?

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Which of the following protons gives an NMR signal with the lowest chemical shift value (farthest upfield) ? Which of the following protons gives an NMR signal with the lowest chemical shift value (farthest upfield) ?   A) 1 B) 2 C) 3 D) 4 E) 5


A) 1
B) 2
C) 3
D) 4
E) 5

F) C) and D)
G) B) and C)

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Mark with an asterisk each carbon that would not produce a signal in the DEPT 13C NMR spectrum of the compound below. Mark with an asterisk each carbon that would not produce a signal in the DEPT <sup>13</sup>C NMR spectrum of the compound below.

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Predict the number of signals expected,their splitting,and their relative area in the 1H NMR spectrum of CH3CH2OCH3.

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3 signals: (3H,tripl...

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Determine the number of signals for isopentylamine in the 1H NMR spectrum.


A) 2
B) 3
C) 4
D) 5
E) 6

F) A) and E)
G) A) and D)

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How many signals will be observed in the proton NMR spectrum of the following molecule? How many signals will be observed in the proton NMR spectrum of the following molecule?   A) 4 B) 5 C) 6 D) 7 E) 8


A) 4
B) 5
C) 6
D) 7
E) 8

F) None of the above
G) All of the above

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Deduce the identity of the following compound from the 1H NMR spectral data given. C3H6Br2 : two peaks: a 2H quintet and a 4H triplet

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Which of the compounds below most closely matches the following 1H NMR data: 7.6 (2H,d),7.3 (2H,d),3.5 (3H,s),2.2 (3H,s)? Which of the compounds below most closely matches the following <sup>1</sup>H NMR data: 7.6 (2H,d),7.3 (2H,d),3.5 (3H,s),2.2 (3H,s)?

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How many signals would you expect to see in the 1H NMR spectrum of the following compound? How many signals would you expect to see in the <sup>1</sup>H NMR spectrum of the following compound?   A) 5 B) 4 C) 2 D) 3 E) 1


A) 5
B) 4
C) 2
D) 3
E) 1

F) A) and B)
G) A) and E)

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Can alkenes and aromatics be easily distinguished from each other in an 13C NMR spectrum?

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Alkenes are in the range of 10...

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How many distinct carbon signals are expected in the proton-decoupled 13C NMR spectrum of the compound below? How many distinct carbon signals are expected in the proton-decoupled <sup>13</sup>C NMR spectrum of the compound below?

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Provide the structure that is consistent with the data below. C6H11N IR (cm-1): 2950,2230 1H NMR (δ): 1.7 (quintet,1H),1.2 (m,4H),0.9 (t,6H) 13C NMR (δ): 95 (s),45 (d),25 (t),18 (q)

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What is the ratio of the protons in the following compound? What is the ratio of the protons in the following compound?   A) 3:3:3:2 B) 6:3:2 C) 9:2 D) 3:2 E) 6:2


A) 3:3:3:2
B) 6:3:2
C) 9:2
D) 3:2
E) 6:2

F) C) and D)
G) All of the above

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How many distinct triplets would you expect in the 1H NMR of the compound below? How many distinct triplets would you expect in the <sup>1</sup>H NMR of the compound below?   A) 0 B) 2 C) 4 D) 6 E) 8


A) 0
B) 2
C) 4
D) 6
E) 8

F) B) and C)
G) B) and D)

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Deduce the identity of the following compound from the 1H NMR spectral data given. C7H12O4 : δ 1.1 (6H,triplet),3.4 (2H,singlet),4.2 (4H,quartet)(ppm)

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Give the structure for the compound that has a formula of C11H16O and the following 1H NMR and 13C NMR spectra.Label the hydrogens and the carbons. 1H NMR spectrum: 1.3 ppm,(d,6H); 3.1 ppm (sept,1H); 3.2 ppm (s,3H); 4.6 ppm (s,2H),7.1 ppm (d,2H),7.1 ppm (d,2H) 13C NMR spectrum: 24.4 ppm (CH3); 31.7 ppm (CH); 53.5 ppm (CH3); 77.9 ppm (CH2); 126.2 ppm (CH); 127.3 ppm (CH); 134.4 ppm (C); and 147.8 ppm (C).

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In the proton NMR spectrum,the indicated CH2 group will show up as a In the proton NMR spectrum,the indicated CH<sub>2</sub> group will show up as a   A) singlet. B) doublet. C) triplet. D) quartet. E) quintet.


A) singlet.
B) doublet.
C) triplet.
D) quartet.
E) quintet.

F) A) and E)
G) A) and D)

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What is indicated by a cross peak in the COSY spectrum of a compound?

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The dots that are not on the d...

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